The 31-year-old England striker opened the scoring with a composed penalty in the 15th minute, awarded after a foul on Michael Olise in the box.
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Kane then set up Kingsley Coman to double Bayern’s lead just before halftime and later sealed the victory by tapping in his second goal in the 51st minute at the Allianz Arena.
Kane remains the Bundesliga’s top scorer with 11 goals and boasts an impressive 60 goal contributions in 41 league appearances, totaling 47 goals and 13 assists.
The victory halted Union Berlin’s three-match unbeaten streak, dropping them to sixth place, while Bayern notched their third consecutive league win.
Vincent Kompany’s side now hopes to carry their league momentum into the Champions League as they face Benfica this week, having won one and lost two of their group-stage matches so far.
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